Him
1 used as the object of a verb,
When did you see him?
after the verb be
It's him.
, or after a preposition,
He took the children with him
to refer to a male person or animal that has already been mentioned or is easily identified
Peter is my friend , I love him .
He
(used as the subject of a verb)
1 a male person or animal that has already been mentioned or is easily identified
Everyone liked my father—he was the perfect gentleman.
He (= the man we are watching) went through that door.
more info : http://oaadonline.oxfordlearnersdictionaries.com/dictionary/he

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